WAYNE PIGMENT CORP -- LEAD CHROMATE -- 6810-00N042615
===================== Product Identification ===================== Product ID:LEAD CHROMATE MSDS Date:01/08/1992 FSC:6810 NIIN:00N042615 === Responsible Party === Company Name:WAYNE PIGMENT CORP Address:306 N MILWAUKEE ST City:MILWAUKEE State:WI ZIP:53202 Country:US Info Phone Num:414-225-2400 Emergency Phone Num:414-225-2400;800-424-9300(CHEMTREC) CAGE:IO550 === Contractor Identification === Company Name:WAYNE PIGMENT CORP Address:306 N MILWAUKEE ST Box:City:MILWAUKEE State:WI ZIP:53202 Country:US Phone:414-225-2400 CAGE:IO550 ============= Composition/Information on Ingredients ============= Ingred Name:ING 15:LOWER EYELIDS UNTIL NO EVID OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MED ATTN IMMED. INGEST: USE GASTRIC(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: LAVAGE OR EMESIS. MAINTAIN BLOOD PRESSURE & AIRWAY. GIVE OXYGEN IF NOT BREATHING. DO NOT PERFORM (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: GASTRIC LAVAGE OR EMESIS IF VICTIM IS UNCON. GET MED ATTN IMMED. ADMIN OF GASTRIC LAVAGE OR OXYGEN (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: SHOULD BE PERFORMED BY QUALIFIED PERS. ANTIDOTE: FOR INFORMATION CONTACT NEHC . RTECS #:9999999ZZ Ingred Name:SPILL PROC: FROM SPILL AREA. FOR LARGER SPILLS, DIKE FAR AHEAD OF SPILL FOR LATER DISP. KEEP UNNEC PEOPLE AWAY. (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: ISOLATE HAZ AREA & DENY ENTRY. CALIFORNIA SAFE DRINKING WATER & TOX ENFORCEMENT ACT OF 1986 PROHIBITS (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: CONTAMINATING ANY KNOWN SOURCE OF DRINKING WATER W/SUBSTANCES KNOWN TO CAUSE CANCER &/OR REPRO TOXICITY. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: TOXICITY & MUST BE DISPOSED OF I/A/W 40 CFR PART 262. EPA HAZ WASTE NUMBER:D008. REGULATORY (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23: LEVEL OF CHROMIUM: 5.0 MG/L. EPA HAZARDOUS WASTE NUMBER: D007. RTECS #:9999999ZZ Ingred Name:EXPLAN OF CARCIN: ANNUAL REPORT ON CARCINOGENS, 1994: KNOWN TO BE CARCINOGEN. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: INFO & HNDLG & EXPOS INFO . INHAL:FREQUENT & LONG-TERM INHAL MAY CAUSE NOSE-BLEEDS, (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: ULCERATION & PERFORATION OF NASAL SEPTUM, ACUTE HEPATITIS, LEAD POISONING & LUNG CANCER. SYMPS OF LEAD (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: POISONING INCL FACIAL PALLOR, "LEAD LINE" IN GUMS, MILD JAUNDICE, ANEMIA, EXCESSIVE LEAD CONCS IN URINE & (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:BLOOD & PERIPHERAL NEUROPATHY. PERIPHERAL NERVE AFFECTED MOST FREQUENTLY IS RADIAL NERVE WHICH CAUSES CNDTN(ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:KNOWN AS "WRIST DROP." EXCESS RISK FOR LUNG & SINONASAL CANCER REPORTED IN WORKERS IN CHROMATE PRODUCTION,(ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: CHROMATE PIGMENT PRODUCTION & CHROMIUM PLATING INDUSTRIES. OVEREXP TO LEAD IMPAIRS REPRO SYS OF BOTH MEN (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: & WOMEN. CHILDREN BORN OF PARENTS, EITHER ONE OF WHOM WAS EXPOSED TO EXCESS LEAD LEVELS, ARE MORE LIKELY (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: TO HAVE BIRTH DEFECTS, MENTAL RETARDATION, BEHAVIORAL DISORDERS IN FIRST YR OF CHILDHOOD. SKIN: SENSIT (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: DERM ACCOMPANIED BY ECZEMA IS COMMON. EYES: CONJ MAY OCCUR. INGEST: MAY CAUSE LEAD POISONING W/FACIAL (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: PALLOR, "LEAD LINE" IN GUMS, EXCESS CONC OF LEAD IN URINE & BLOOD & PERIPHERAL NEUROPATHY RSLTG IN (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: "WRIST DROP." TOXICITY: TARGET EFTS:SENSITIZER - SKIN; NEUROTOXIN. POISONING MAY ALSO AFFECT CNS, GI (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: TRACT, BLOOD & KIDNEY. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: MED ATTN IMMED. EYES: FLUSH IMMED W/LG AMTS OF WATER OR NORM SALINE, OCCASNLY LIFTING UPPER & (ING 16) RTECS #:9999999ZZ Ingred Name:LEAD CHROMATE CAS:7758-97-6 RTECS #:GB2975000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: 30 MG/M3 IMMED DANGEROUS TO LIFE & HLTH. MAY CAUSE COUGH, NAUS, METALLIC TASTE & IRRIT OF RESP TRACT. IF ABSORPTION IS SUFFICIENT, ABDOM PAIN, LEG CRAMPS, MUSC WEAK, PARESTHESIAS, DEPRES S & COMA MAY OCCUR. SKIN: CNTCT MAY PRDCE SKIN LESIONS (CHROME ULCERS) WHICH ARE PAINLESS BUT SLOW TO (EFTS OF OVEREXP) Explanation of Carcinogenicity:LEAD CHROMATE: IARC MONOGRAPHS ON EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 49, 1990:GROUP 1. NTP 7TH (ING 2) Effects of Overexposure:HLTH HAZ: HEAL & SCAR TISS. EYE: MAY CAUSE IRRIT, LACRIM & CONJ. INGEST: MAY CAUSE METALLIC TASTE, INTENSE THIRST, ABDOM PAIN, VOMIT, GI IRRIT. DEATH MAY RSLT FROM UREMIA. CHRONIC: LEAD APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST (ING 3) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, GIVE ARTF RESP. CHECK BLOOD PRESS & ADMIN OXYGEN IF AVAIL. KEEP AFFECTED PERSON WARM & AT REST. ADMIN OF OXYGEN SHOULD BE PERFORM ED BY QUALIFIED PERS. GET MD IMMEDIATELY. SKIN: REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP OR MILD DETERGENT & CONTINUE UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MIN). GET(ING 15) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNR FROM FIRE AREA IF ABLE TO W/OUT RISK. USE AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE. AVOID (SUPDAT) Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATL. STOP LEAK IF YOU CAN DO IT W/OUT RISK. FOR SM SPILLS, TAKE UP W/SAND OR OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP. FOR SM DRY SPILLS, W/CLEAN SHOVEL, PLACE MATL I NTO CLEAN, DRY CNTNR & COVER. MOVE CNTNRS (ING 20) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:MAY BURN BUT DOES NOT IGNITE READILY. PREVENT DISPERSION OF DUST IN AIR. DO NOT ALLOW SPILLED MATERIAL TO CONTAMINATE WATER SOURCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN THE WORKPLACE, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND MUST BE APPROVED BY NIOSH. FOR A LIST OF SPECIFI C RESPIRATORS CONTACT NEHC . Ventilation:PROVIDE LOC EXHST OR PROCESS ENCLOSURE VENT TO MEET PUBLISHED EXPOS LIMS. VENT SHOULD MEET REQS IN 20 CFR 1910.1025(E). Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER. APPROP PROT(IMPERVIOUS) CLTHG & EQUIP TO PVNT PRLNGD SKIN CNTCT W/SUBSTANCE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROCS: BRTHG DUSTS & FUMES FROM BURNING MATL. KEEP UPWIND. MATL TO AVOID: & 1(2',4'-DINITROBENZENEAZO)2-HYDROXYNAPTHALENE: POSS VIOLENT EXPLO. FERRIC FERROCYANIDE: FORMS FRICTION-SENSITIVE MIXTURE. SULFUR, TANTALUM: FORMS PYROPHORIC MIXTURE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:1551F,844C Spec Gravity:5.40-5.60 Solubility in Water:58 PPB Appearance and Odor:AN ODORLESS FINE YELLOW TO YELLOW-ORANGE POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALUMINUM, DINITRONAPHTHALENE:FORMS IGNIT MIX. AZO-DYESTUFFS, 1(4'-CHLORO-2'-NITROBENZENEAZO) -2HYDROXYNAPTHALENE(SUPDAT) Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HIGHLY TOXIC OXIDES OF LEAD AND CHROMIUM. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FED, STATE & LOCAL REGS WHEN STORING/DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE CNTCT THE DISTRICT DIRECTOR OF EPA. REGULATORY LEVEL OF LEAD:5.0 MG/L. MATLS CONTAINING LEAD AT/ABOVE REGUL ATORY LEVEL MEET THE EPA CHARACTS OF (ING 23) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.